Tetrahedron Letters p. 4447 - 4448 (1993)
Update date:2022-08-02
Topics:
Sunazuka, Toshiaki
Nagamitsu, Tohru
Tanaka, Haruo
Omura, Satoshi
Sprengeler, Paul A.
Smith III, Amos B.
The four stereoisomers of 3-hydroxyleucine have been prepared in high overall yield and enantiomeric purity. Key steps include Sharpless asymmetric epoxidation, benzyl isocyanate-induced epoxide opening, and epimerization of an intermediate oxazolidinone ester.
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(2013)
