Transformations of o-nitroarylallyl carbanions. Synthesis of quinoline N-oxides and N-hydroxyindoles

DOI: 10.1016/S0040-4020(01)82380-2

Source and publish data:

Tetrahedron p. 5315 - 5326 (1993)

Update date:2022-08-05

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Authors:

Wrobel, Zbigniew

Makosza, Mieczysawa

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Article abstract of DOI:10.1016/S0040-4020(01)82380-2

Nitriles and esters of 2-(o-nitroaryl)crotonic acids are converted under basic conditions into substituted quinoline N-oxides, N-hydroxyindoles and N-hydroxy-2-hydroxymethyl indoles. Factors governing the reaction course and mechanistic pathways are discussed.

Full text of DOI:10.1016/S0040-4020(01)82380-2

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