
Journal of the Chemical Society, Dalton Transactions p. 3001 - 3008 (1993)
Update date:2022-07-29
Topics:
Costella, Luigina
Zotto, Alessandro Del
Mezzetti, Antonio
Zangrando, Ennio
Rigo, Pierluigi
The ligand 1-(diphenylphosphino)-2-(2-pyridyl)ethane (ppye) forms six-co-ordinate species a dangling, P-bound ppye ligand.All these carbonyl derivatives are formed as the kinetically preferred species with a P atom trans to CO, and are converted in solution at room temperature into the thermodynamically preferred isomers in which the P and CO groups are mutually cis.
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Doi:10.1271/bbb.57.1433
(1993)Doi:10.1021/ic4024458
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(1994)