Substituent effects on cyclobutyl and cyclopropylcarbinyl cations

DOI: 10.1021/ja00076a024

Source and publish data:

Journal of the American Chemical Society p. 10645 - 10652 (1993)

Update date:2022-07-29

Topics: Mass spectrometry Nuclear magnetic resonance (NMR) spectroscopy Chemical Synthesis Substituent Effects Experimental terms

Authors:

Wiberg, Kenneth B.

Shobe, David

Nelson, Gordon L.

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Article abstract of DOI:10.1021/ja00076a024

The acetolyses of 3-substituted cyclobutyl tosylates (X = Ar, Cl, and OEt) were examined giving rate constants and product distributions. With the alkyl- and aryl-substituted compounds, the rate-determining step leads to the formation of a bridged cyclobu

Full text of DOI:10.1021/ja00076a024

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