Stereocontrolled syntheses of C-aryl taxanes by intramolecular Heck olefination. Novel instances of diastereofacial guidance by proximal coordination

DOI: 10.1021/ja00124a006

Source and publish data:

Journal of the American Chemical Society p. 5228 - 5234 (1995)

Update date:2022-08-03

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Authors:

Young, Wendy B.

Masters, John J.

Danishefsky, Samuel

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Article abstract of DOI:10.1021/ja00124a006

Stereospecific syntheses of baccatin III constructs bearing an aromatic C-ring (2a and 2b) have been demonstrated. A key step involves the use of an intramolecular Heck olefination reaction to form the C₁₀-C₁₁ bond. Novel stereospeci

Full text of DOI:10.1021/ja00124a006

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