Activation and synthetic applications of thiostannanes. A new method for synthesis of thio- and selenoglycosides

DOI: 10.1016/0040-4039(92)88060-I

Source and publish data:

Tetrahedron Letters p. 239 - 242 (1992)

Update date:2022-08-04

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Authors:

Sato, Tsuneo

Fujita, Yukihiro

Otera, Junzo

Nozaki, Hitosi

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Article abstract of DOI:10.1016/0040-4039(92)88060-I

Exposure of thiostannane to acetyl or methyl glycosides in the presence of a catalytic amount of Bu₂Sn(OTf)₂ provides thioglycosides in good yields. Selenoglycosidation is achieved in a like manner by use of selenostannane.

Full text of DOI:10.1016/0040-4039(92)88060-I

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