Angewandte Chemie - International Edition p. 4405 - 4409 (2019)
Update date:2022-08-03
Topics:
Muessig, Jonas H.
Thaler, Melanie
Dewhurst, Rian D.
Paprocki, Valerie
Seufert, Jens
Mattock, James D.
Vargas, Alfredo
Braunschweig, Holger
The lability of B=B, B?P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.
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