Interaction of Heterocyclic Nitrones With Organometallic Reagents As a Method For the Synthesis of New Types of Nitroxides

DOI: 10.1016/S0040-4020(01)81557-X

Source and publish data:

Tetrahedron p. 10669 - 10692 (1993)

Update date:2022-08-04

Topics:

Authors:

Reznikov, Vladimir A.

Volodarsky, Leonid B.

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Article abstract of DOI:10.1016/S0040-4020(01)81557-X

The reactions of heterocyclic nitroxides: 3-imidazoline-3-oxides, 2H- (4H)-imidazole mono- and dioxides, dihydropyrazine-1,4-dioxides, with organometallic reagents and subsequent oxidation led to heterocyclic nitroxides of 3-(2)-imidazoline and 3-(2)-imidazoline-3-oxide, dihydropyrazine oxide, monocyclic imidazolidine biradicals and stable acyclic nitroxides with hydrogen at the α-carbon atom.

Full text of DOI:10.1016/S0040-4020(01)81557-X

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Product name:1,5,5-trimethyl-2-spirocyclohexyl-4-phenyl-3-imidazoline-3-oxide

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