Novel pathway for the intermolecular cyclization of the ((propargylthio)thiocarbonyl)diphenylphosphine ligand in tungsten complexes

DOI: 10.1021/om00017a009

Source and publish data:

Organometallics p. 1561 - 1563 (1994)

Update date:2022-08-04

Topics:

Authors:

Yih, Kuang-Hway

Lin, Ying-Chih

Cheng, Ming-Chu

Wang, Yu

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The tungsten complex W(CO)₅[PPh₂(CS₂-C₃H₃)] (2) undergoes dimerization, giving W₂(CO)₁₀[P₂-Ph₄(C₈H ₆S₄)] (3). Protonation o

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