Chiral synthesis of (-)-mesembranol starting from D-glucose

DOI: 10.1039/c39940000901

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 901 - 902 (1994)

Update date:2022-08-03

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Authors:

Chida Chida

Sugihara

Ogawa Ogawa

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Article abstract of DOI:10.1039/c39940000901

The chiral synthesis of the Sceletium alkaloid, (-)-mesembranol 1 is described; the cyclohexane ring in 1 is prepared in an optically active form from D-glucose using Ferrier's carbocyclisation reaction and the perhydroindole skeleton is effectively constructed by an intramolecular aminomercuration reaction.

Full text of DOI:10.1039/c39940000901

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