Journal of the Chemical Society. Chemical communications p. 901 - 902 (1994)
Update date:2022-08-03
Topics:
Chida
Sugihara
Ogawa
The chiral synthesis of the Sceletium alkaloid, (-)-mesembranol 1 is described; the cyclohexane ring in 1 is prepared in an optically active form from D-glucose using Ferrier's carbocyclisation reaction and the perhydroindole skeleton is effectively constructed by an intramolecular aminomercuration reaction.
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