Chiral synthesis of (-)-mesembranol starting from D-glucose

DOI: 10.1039/c39940000901

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 901 - 902 (1994)

Update date:2022-08-03

Topics:

Authors:

Chida Chida

Sugihara

Ogawa Ogawa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940000901

The chiral synthesis of the Sceletium alkaloid, (-)-mesembranol 1 is described; the cyclohexane ring in 1 is prepared in an optically active form from D-glucose using Ferrier's carbocyclisation reaction and the perhydroindole skeleton is effectively constructed by an intramolecular aminomercuration reaction.

Full text of DOI:10.1039/c39940000901

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

Cas No:156487-73-9

R&D Labs maybe for 156487-73-9

Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
Changzhou Kingyo Chemical Corporation Ltd.

website:http://www.kingyochem.com

Contact:+86-519-85105717

Address:19# Wuqing North Road, Changzhou , Jiangsu, China
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province

Relevant to this article

DBU-Catalyzed Rearrangement of Secondary Propargylic Alcohols: An Efficient and Cost-Effective Route to Chalcone Derivatives

Doi:10.1055/s-0040-1707909
(2020)
Synthesis and pH-responsive assembly of methoxy poly(ethylene glycol)-b-poly(ε-caprolactone) with pendant carboxyl groups

Doi:10.1002/pola.26987
(2014)
Extending the scope of the carbonyl facilitated triplet excited state towards visible light excitation

Doi:10.1039/c8cp01023d
(2018)
Biosynthesis of the N–N-Bond-Containing Compound l-Alanosine

Doi:10.1002/anie.201913458
(2020)
On the Reaction of Dithiocarbamates with Nitrogen-Containing Derivatives of Oxalic Acid

Doi:10.1007/BF00810842
(1989)
α-Halogenation as a Strategy to Functionalize Cyclohexa-2,4-dienones

Doi:10.1055/s-0036-1588359
(2017)

Article Doi