A synthesis of (±)-Supinidine via an intramolecular carbenoid-thioimide coupling reaction

DOI: 10.1016/S0040-4039(00)73088-7

Source and publish data:

Tetrahedron Letters p. 3747 - 3748 (1994)

Update date:2022-08-03

Topics:

Authors:

Kim, Guncheol

Kang, Sunwha

Keum, Gyochang

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Article abstract of DOI:10.1016/S0040-4039(00)73088-7

Intramolecular diazoketoester-thioimide annulation reaction in the presence of rhodium(II) acetate dimer provided a new way to pyrrolizidine skeletons (±)-Supinidine was synthesized by subsequent manipulations.

Full text of DOI:10.1016/S0040-4039(00)73088-7

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Product name:1-Pyrrolidinebutanoic acid, -bta-,2-dioxo-5-thioxo-, methyl ester

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