Journal of the American Chemical Society
Communication
(h) Matsubara, T.; Asako, S.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc.
2014, 136, 646.
ASSOCIATED CONTENT
* Supporting Information
Experimental details and characterization data. This material is
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S
(8) For selected recent reports on allylic sp3 C−H amination, see:
(a) Rice, G. T.; White, M. C. J. Am. Chem. Soc. 2009, 131, 11707.
(b) Luzung, M. R.; Lewis, C. A.; Baran, P. S. Angew. Chem., Int. Ed. 2009,
48, 7025. (c) Yin, G.; Wu, Y.; Liu, G. J. Am. Chem. Soc. 2010, 132, 11978.
(9) For intramolecular sp3 C−H amination, see: (a) Neumann, J. J.;
AUTHOR INFORMATION
Corresponding Author
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Rakshit, S.; Droge, T.; Glorius, F. Angew. Chem., Int. Ed. 2009, 48, 6892.
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(b) He, G.; Zhao, Y.; Zhang, S.; Lu, C.; Chen, G. J. Am. Chem. Soc. 2012,
134, 3. (c) Nadres, E. T.; Daugulis, O. J. Am. Chem. Soc. 2012, 134, 7.
(d) He, G.; Zhang, S.-Y.; Nack, W. A.; Li, Q.; Chen, G. Angew. Chem., Int.
Ed. 2013, 52, 11124. (e) Zhang, Q.; Chen, K.; Rao, W.; Zhang, Y.; Chen,
F.-J.; Shi, B.-F. Angew. Chem., Int. Ed. 2013, 52, 13588. (f) Nguyen, Q.;
Nguyen, T.; Driver, T. G. J. Am. Chem. Soc. 2013, 135, 620.
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
(10) For selected reports on intermolecular sp3 C−H amination, see:
(a) Thu, H.-Y.; Yu, W.-Y.; Che, C.-M. J. Am. Chem. Soc. 2006, 128, 9048.
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This research was supported by the Institute of Basic Science
(IBS). We thank Mr. Jin Kim for X-ray crystallographic analysis.
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(b) Iglesias, A.; Alvarez, R.; de Lera, A. R.; Muniz, K. Angew. Chem., Int.
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Ed. 2012, 51, 2225.
(11) For related reviews of sp3 C−H amination, see: (a) Collet, F.;
Dodd, R. H.; Dauban, P. Chem. Commun. 2009, 5061. (b) Jazzar, R.;
Hitce, J.; Renaudat, A.; Sofack-Kreutzer, J.; Baudoin, O. Chem.Eur. J.
2010, 16, 2654. (c) Li, H.; Li, B.-J.; Shi, Z.-J. Catal. Sci. Technol. 2011, 1,
191. (d) Jeffrey, J. L.; Sarpong, R. Chem. Sci. 2013, 4, 4092.
(12) (a) Cho, S. H.; Kim, J. Y.; Lee, S. Y.; Chang, S. Angew. Chem., Int.
Ed. 2009, 48, 9127. (b) Kim, J. Y.; Cho, S. H.; Joseph, J.; Chang, S.
Angew. Chem., Int. Ed. 2010, 49, 9899. (c) Cho, S. H.; Yoon, J.; Chang, S.
J. Am. Chem. Soc. 2011, 133, 5996. (d) Kim, H. J.; Kim, J.; Cho, S. H.;
Chang, S. J. Am. Chem. Soc. 2011, 133, 16382.
(13) (a) Kim, J. Y.; Park, S. H.; Ryu, J.; Cho, S. H.; Kim, S. H.; Chang, S.
J. Am. Chem. Soc. 2012, 134, 9110. (b) Ryu, J.; Shin, K.; Park, S. H.; Kim,
J. Y.; Chang, S. Angew. Chem., Int. Ed. 2012, 51, 9904. (c) Shin, K.; Baek,
Y.; Chang, S. Angew. Chem., Int. Ed. 2013, 52, 8031. (d) Kim, J.; Kim, J.;
Chang, S. Chem.Eur. J. 2013, 19, 7328. (e) Ryu, J.; Kwak, J.; Shin, K.;
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Y.; Chang, S. J. Org. Chem. 2013, 78, 11102. (g) Park, S. H.; Park, Y.;
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