Total synthesis of the major metabolites of gomisin A. Synthesis of homochiral met A-II, met A-III, met D, and met F

DOI: 10.3987/com-95-s45

Source and publish data:

Heterocycles p. 359 - 374 (1996)

Update date:2022-08-03

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Authors:

Tanaka, Masahide

Mitsuhashi, Hiroshi

Marano, Masao

Wakamatsu, Takeshi

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Article abstract of DOI:10.3987/com-95-s45

The total syntheses of the metabolites of gomisin A (1) were achieved. By the Mukaiyama hydration or the successive double bond migration, lactone ring reduction, glycol formation, and reduction, the homochiral lactones (10a-c) provided met A-III (3), A-II (2), D (5), and F (7).

Full text of DOI:10.3987/com-95-s45

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