Chemistry Letters p. 1099 - 1100 (1998)
Update date:2022-07-29
Topics:
Matsubara, Hiroshi
Shimura, Tomohiro
Hasegawa, Akio
Semba, Miki
Asano, Kaori
Yamamoto, Koji
Fullerene tweezers which have a rigid acetylenic spacers were synthesized and their inclusion abilities for C60 were examined by UV spectroscopy. From the spectra, the association constants were determined using Benesi-Hildebrand method. Fullerene tweezers with a 1,4-bis(4-oxycarbonylphenyl)butadiyne spacer showed the highest association constant for C60 (39300±250 dm3mol-1 in benzene).
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