The Diastereospecific Synthesis of New 2',3'-Cis-α-Fused Carbocyclic Nucleosides

DOI: 10.1016/0040-4020(94)00950-Y

Source and publish data:

Tetrahedron p. 329 - 343 (1995)

Update date:2022-09-26

Topics:

Authors:

Papchikhin, A.

Agback, P.

Plavec, J.

Chattopadhyaya, J.

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Article abstract of DOI:10.1016/0040-4020(94)00950-Y

The first diastereospecific synthesis of <3.3.0>- and <3.4.0>-α-cis-fused-carbocyclic nucleosides 10,12 and 20, starting directly from 2'-O-(TBDMS) or 3'-O-(TBDMS) derivatives of 5'-O-MMTr-2',3'-seco-ribo-thimidines, 1 and 13 (ref. 4), have been reported.

Full text of DOI:10.1016/0040-4020(94)00950-Y

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Product name:5'-O-(p-monomethoxytrityl)-2'-deoxy-2'-C-(E-carbethoxymethylidene)-2',3'-secoribothymidine

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