Practical total synthesis of a naturally occurring thielocin via the regioselective arylation of a cyclic boronate

DOI: 10.1016/0040-4039(94)80108-8

Source and publish data:

Tetrahedron Letters p. 7747 - 7750 (1994)

Update date:2022-07-30

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Authors:

Genisson, Yves

Young, Robert N.

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Article abstract of DOI:10.1016/0040-4039(94)80108-8

The first total synthesis of thielocin B (2) has been achieved. Lewis acid-catalyzed arylation of the readily available cyclic boronate 8 provided the central portion of the molecule in a regiocontrolled manner. The desired natural compound 2 was then obt

Full text of DOI:10.1016/0040-4039(94)80108-8

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