Free-radical oxidation of para-substituted phenols by hypervalent tert-butylperoxiodane and tert-butyl hydroperoxide: Synthesis of 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones

DOI: 10.1016/S0040-4039(97)00781-8

Source and publish data:

Tetrahedron Letters p. 3927 - 3930 (1997)

Update date:2022-08-05

Topics:

Authors:

Ochiai, Masahito

Nakanishi, Akinobu

Yamada, Akiko

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Article abstract of DOI:10.1016/S0040-4039(97)00781-8

Oxidation of 4-alkylphenols 1 by 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one (2) in the presence of tert-butyl hydroperoxide affords selectively 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones 3 in good yields. Evidence for the involvement of free-radicals is reported.

Full text of DOI:10.1016/S0040-4039(97)00781-8

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Product name:4-(tert-butylperoxy)-4-isopropyl-2,5-cyclohexadien-1-one

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