Free-radical oxidation of para-substituted phenols by hypervalent tert-butylperoxiodane and tert-butyl hydroperoxide: Synthesis of 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones

DOI: 10.1016/S0040-4039(97)00781-8

Source and publish data:

Tetrahedron Letters p. 3927 - 3930 (1997)

Update date:2022-08-05

Topics:

Authors:

Ochiai, Masahito

Nakanishi, Akinobu

Yamada, Akiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00781-8

Oxidation of 4-alkylphenols 1 by 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one (2) in the presence of tert-butyl hydroperoxide affords selectively 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones 3 in good yields. Evidence for the involvement of free-radicals is reported.

Full text of DOI:10.1016/S0040-4039(97)00781-8

Products guided by the article

Product name:4-(tert-butylperoxy)-4-isopropyl-2,5-cyclohexadien-1-one

Cas No:160010-66-2

R&D Labs maybe for 160010-66-2

Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
SuZhou Yacoo Science Co., Ltd

website:https://www.yacoo.com.cn/en/

Contact:86-512-87182055

Address:No.112 Xinqing Rd, Suzhou Industrial Park, China, 215125, China
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai

Relevant to this article

An enantioselective synthesis of the C₂₄-C₄₀ fragment of (-)-pulvomycin

Doi:10.1039/c4cc01338g
(2014)
Synthesis, Molecular Structure, Fluxional Behavior, and Tricarbonyliron Transfer Reactions of (η⁴-1-Azabuta-1,3-diene)tricarbonyliron Complexes

Doi:10.1002/(SICI)1099-0682(199807)1998:7<993::AID-EJIC993>3.0.CO;2-6
(1998)
New synthesis of diazepino[3,2,1-ij]quinoline and pyrido[1,2,3-de] quinoxalines via addition-elimination followed by cycloacylation

Doi:10.1002/jhet.1594
(2014)
Synthesis of (+)-cis-N-(4-isothiocyanatobenzyl)-N-normetazocine, an isothiocyanate derivative of N-benzylnormetazocine as acylant agent for the σ₁ receptor

Doi:10.1021/jm010501a
(2002)
A synthesis of functionalized 2-imino-1,3-thiazoles from tetramethylguanidine, isothiocyanates, and 2-chloro-1,3-dicarbonyl compounds

Doi:10.1007/s13738-013-0299-0
(2014)
Addition of N-benzylhydrazine to sugar δ-enlactones

Doi:10.1016/S0040-4020(01)85245-5
(1994)

Article Doi