Angewandte Chemie - International Edition p. 1638 - 1641 (2015)
Update date:2022-08-05
Topics:
Niljianskul, Nootaree
Zhu, Shaolin
Buchwald, Stephen L.
The synthesis of α-aminosilanes by a highly enantio- and regioselective copper-catalyzed hydroamination of vinylsilanes is reported. The system employs Cu-DTBM-SEGPHOS as the catalyst, diethoxymethylsilane as the stoichiometric reductant, and O-benzoylhyd
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