Synthesis of the Ziegler key intermediate and related precursors for the synthesis of forskolin and erigerol in enantiomerically pure form

Article abstract of DOI:10.1080/00397919408010600

The Ziegler key intermediate 5, previously used in three total synthesis of forskolin (1), and the intermediate 4, potentially useful for the synthesis of erigerol (2), were obtained in optically pure form by the resolution of the allylic alcohol 7a with R-(-)-O-methylmandelic acid.

Full text of DOI:10.1080/00397919408010600

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Synthetic Communications: An
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Organic Chemistry
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Synthesis of the Ziegler Key
Intermediate and Related
Precursors for the Synthesis
of Forskolin and Erigerol in
Enantiomerically Pure Form
Marcelo D. Preite a & Edmundo A. Rúveda a
a Institute de Quimica Orgánica de Sintesis CONICET-
Universidad Nacional de Rosario Facultad de
Ciencias Bioquimicas y Farmacéuticas Casilla de
Correo 991 , 2000, Rosario, Argentina
Published online: 23 Sep 2006.
To cite this article: Marcelo D. Preite & Edmundo A. Rúveda (1994) Synthesis of the
Ziegler Key Intermediate and Related Precursors for the Synthesis of Forskolin and
Erigerol in Enantiomerically Pure Form, Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 24:19, 2809-2825,
DOI: 10.1080/00397919408010600
To link to this article: http://dx.doi.org/10.1080/00397919408010600
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