Vinylidene transition metal complexes XXXIV The preparation and structure of neutral vinylidene and allenylidene ruthenium(II) compounds of the half-sandwich type containing iPr2PCH2CO2Me as supporting ligand.

DOI: 10.1016/0022-328X(94)00015-5

Source and publish data:

Journal of Organometallic Chemistry p. 169 - 176 (1995)

Update date:2022-08-05

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Authors:

Braun, T.

Steinert, P.

Werner, H.

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Article abstract of DOI:10.1016/0022-328X(94)00015-5

The reaction of the tetrameric compound *Ru(μ₃-Cl)>4 (1; Cp^* = C5Me5) with ⁱPr2PCH2CO2Me gives the monomeric species *RuCl<κ²(P,O)-ⁱPr2PCH2CO2Me>> (2) which is an excellent

Full text of DOI:10.1016/0022-328X(94)00015-5

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Product name:[(C₅Me₅)RuCl(=C=CHCPh₂OH)((i)-Pr₂PCH₂CO₂Me)]

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