Hydroruthenation of Prop-2-ynyltriphenylphosphonium Bromide: Synthesis, Crystal Structure and Reactions of PF6

DOI: 10.1039/c39950000369

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 369 - 370 (1995)

Update date:2022-08-04

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Authors:

Alcock, Nathaniel W.

Cartwright, Jonathan

Hill, Anthony F.

Marcellin, Monique

Rawles, Heath M.

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Article abstract of DOI:10.1039/c39950000369

The reaction of the complex with prop-2-ynyltriphenylphosphonium bromide (Br) followed by NH4PF6 provides the crystallographically characterised salt PF6 which by virtue of the coordinative uns

Full text of DOI:10.1039/c39950000369

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Product name:RuBr(CO)[P(C₆H₅)3]2CHCHCH₂P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=RuBr(CO)[P(C₆H₅)3]2CHCHCH₂P(C₆H₅)3PF₆

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