Total Synhesis of Balanol, Part 1. Enantioselective Synthesis of the Hexahydroazepine Ring via Chiral Epoxides and Azidirines

DOI: 10.1016/0040-4020(95)00264-9

Source and publish data:

Tetrahedron p. 6061 - 6070 (1995)

Update date:2022-08-04

Topics:

Authors:

Tanner, David

Almario, Antonio

Hoegberg, Thomas

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Article abstract of DOI:10.1016/0040-4020(95)00264-9

Three differents routes to the hexahydroazepine unit of the natural products balanol (1) and ophicordin (2) are described.The common starting material is the chiral epoxy alcohol 3 which is converted to the balanol degradation product 10 (Scheme 1) or to

Full text of DOI:10.1016/0040-4020(95)00264-9

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