Amphiphilic Terpyridine Complexes of Ruthenium and Rhodium displaying Lyotropic Mesomorphism

DOI: 10.1039/DT9950001769

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1769 - 1774 (1995)

Update date:2022-07-29

Topics:

Authors:

Holbrey, John D.

Tiddy, Gordon J. T.

Bruce, Duncan W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001769

New 4'-alkyl-substituted 2,2':6',2''-terpyridine (4'R-terpy) compounds have been synthesised from 4'-methyl-2,2':6',2''-terpyridine and an appropriate 1-bromoalkane and complexed with ruthenium and rhodium to yield new bis(terpyridine) complexes (2+) (R = C19H39 or C31H63) and (3+) (R = C19H39) as chloride and hexafluorophosphate salts.These complexes are amphiphilic being structurally related to surfactant tris(bipyridine)ruthenium complexes.Both ruthenium and rhodium complexes with R = C19H39 and chloride counter ions show lyotropic mesomorphism in water, and the ruthenium complex with R = C31H63 shows mesophase formation in ethylene glycol.

Full text of DOI:10.1039/DT9950001769

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4'-Hentriacontyl-2,2':6',2''-terpyridine

Cas No:167026-72-4

R&D Labs maybe for 167026-72-4

JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.

Relevant to this article

Benzoyl-substituted (η⁶-arene)tricarbonylchromium complexes: Synthesis and structure

Doi:10.1016/j.jorganchem.2006.10.055
(2007)
Evaluation of polymer-supported vinyltin reagents in the Stille cross-coupling reaction

Doi:10.1016/j.tetlet.2007.01.028
(2007)
Azobenzene derivatives carrying a nitroxide radical

Doi:10.1021/jo062266f
(2007)
Highly selective copper-catalyzed ring expansion of vinyl thiiranes: Application to synthesis of biotin and the heterocyclic core of plavix

Doi:10.1021/ja069059h
(2007)
Selective thiylation of 1-vinylpyrrole-2-carbaldehydes: Synthesis of the novel pyrrole synthons 2-[bis(ethylsulfanyl)methyl]-1-vinylpyrroles and 1-(2-ethylthioethyl)pyrrole-2-carbaldehydes

Doi:10.1055/s-2006-958975
(2007)
Synthesis and structure-activity relationship of N-acyl-Gly-, N-acyl-Sar- and N-blocked-boroPro inhibitors of FAP, DPP4, and POP

Doi:10.1016/j.bmcl.2006.11.072
(2007)

Article Doi