Amphiphilic Terpyridine Complexes of Ruthenium and Rhodium displaying Lyotropic Mesomorphism

DOI: 10.1039/DT9950001769

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1769 - 1774 (1995)

Update date:2022-07-29

Topics:

Authors:

Holbrey, John D.

Tiddy, Gordon J. T.

Bruce, Duncan W.

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Article abstract of DOI:10.1039/DT9950001769

New 4'-alkyl-substituted 2,2':6',2''-terpyridine (4'R-terpy) compounds have been synthesised from 4'-methyl-2,2':6',2''-terpyridine and an appropriate 1-bromoalkane and complexed with ruthenium and rhodium to yield new bis(terpyridine) complexes (2+) (R = C19H39 or C31H63) and (3+) (R = C19H39) as chloride and hexafluorophosphate salts.These complexes are amphiphilic being structurally related to surfactant tris(bipyridine)ruthenium complexes.Both ruthenium and rhodium complexes with R = C19H39 and chloride counter ions show lyotropic mesomorphism in water, and the ruthenium complex with R = C31H63 shows mesophase formation in ethylene glycol.

Full text of DOI:10.1039/DT9950001769

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