Prop-2-ynyl Alcohol as a Precursor to the η1-Ethenyl Ligand

DOI: 10.1039/c39950001209

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1209 - 1210 (1995)

Update date:2022-08-03

Topics:

Authors:

O'Connor, Joseph M.

Hiibner, Kristin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001209

In the presence of water the unsaturated iridium(III) metallacyclopentadiene halide complex cyclo(PPh3)2Cl (1, R = CO2Me) undergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the η¹-ethenyl complex cyclo(PPh3)2(CO)(η¹-CH=CH2) (3, R = CO2Me) in quantitative yield.

Full text of DOI:10.1039/c39950001209

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[κ1(C(1),C(4))-C(CO2Me)=C(CO2Me)C(CO2Me)=C(CO2Me)](PPh3)2Ir(CO)(E-CH=CHMe)

Cas No:167385-31-1

R&D Labs maybe for 167385-31-1

Changzhou Welton Chemical Co., Ltd,

Contact:0086-519-85910828,85920537,85912897

Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Nanjing BIODE Co.,Ltd

Contact:+86-025-85553873

Address:Building 27, NO.699-18 XuanWu Avenue, Nanjing, Jiangsu, P.R.China.
Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China

Relevant to this article

Michael additions of 3,3-dimethylacrylamides and amines: Synthesis of the growth hormone secretagogue L-692,585

Doi:10.1080/00397919508015901
(1995)
Trapping of iminiums by the indole nucleus during catalytic hydrogenation of nitriles: A rapid synthesis of tetrahydro-β-carbolines

Doi:10.1016/0040-4039(95)00293-L
(1995)
Oxidation of substrates by an iridium dioxygen complex: Intramolecular oxidation of carbon monoxide and activation of a carbonyl group by attack of a heterocyclic nitrogen

Doi:10.1021/om00010a044
(1995)
An improvede synthesis of 1-(2-deoxy-β-D-erythro-pentofur-anosyl)quinazoline-2,4(3H)-dione and its incorporation into G-rich triple helix forming oligonucleotides

Doi:10.1080/15257779508014652
(1995)
Doi:10.1021/ja01062a038
(1964)
SYNTHESIS OF SOME DERIVATIVES OF 8-AMINOMETHYL- AND 8-AZOLYLMETHYL-2-PHENYL-3H-QUINAZOLINE-4-THIONES

Doi:10.1135/cccc19950705
(1995)

Article Doi