Prop-2-ynyl Alcohol as a Precursor to the η1-Ethenyl Ligand

DOI: 10.1039/c39950001209

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1209 - 1210 (1995)

Update date:2022-08-03

Topics:

Authors:

O'Connor, Joseph M.

Hiibner, Kristin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001209

In the presence of water the unsaturated iridium(III) metallacyclopentadiene halide complex cyclo(PPh3)2Cl (1, R = CO2Me) undergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the η¹-ethenyl complex cyclo(PPh3)2(CO)(η¹-CH=CH2) (3, R = CO2Me) in quantitative yield.

Full text of DOI:10.1039/c39950001209

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[κ1(C(1),C(4))-C(CO2Me)=C(CO2Me)C(CO2Me)=C(CO2Me)](PPh3)2Ir(CO)(E-CH=CHMe)

Cas No:167385-31-1

R&D Labs maybe for 167385-31-1

Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
JiangXi Keyuan Biopharma Co., LTD.

Contact:+86-563-6833666

Address:Guangde Fine Chemical Zone, Anhui Province, China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China

Relevant to this article

Michael additions of 3,3-dimethylacrylamides and amines: Synthesis of the growth hormone secretagogue L-692,585

Doi:10.1080/00397919508015901
(1995)
Trapping of iminiums by the indole nucleus during catalytic hydrogenation of nitriles: A rapid synthesis of tetrahydro-β-carbolines

Doi:10.1016/0040-4039(95)00293-L
(1995)
Oxidation of substrates by an iridium dioxygen complex: Intramolecular oxidation of carbon monoxide and activation of a carbonyl group by attack of a heterocyclic nitrogen

Doi:10.1021/om00010a044
(1995)
An improvede synthesis of 1-(2-deoxy-β-D-erythro-pentofur-anosyl)quinazoline-2,4(3H)-dione and its incorporation into G-rich triple helix forming oligonucleotides

Doi:10.1080/15257779508014652
(1995)
Doi:10.1021/ja01062a038
(1964)
SYNTHESIS OF SOME DERIVATIVES OF 8-AMINOMETHYL- AND 8-AZOLYLMETHYL-2-PHENYL-3H-QUINAZOLINE-4-THIONES

Doi:10.1135/cccc19950705
(1995)

Article Doi