Inorganic Chemistry p. 470 - 476 (1981)
Update date:2022-07-30
Topics:
Dixon, Nicholas E.
Jackson, W. Gregory
Lancaster, Martin J.
Lawrance, Geoffrey A.
Sargeson, Alan M.
Facile synthetic routes to cobalt(III) amine complexes of the labile unidentate trifluoromethanesulfonate anion (CF3SO3-), namely, Co(NH3)5(OSO2CF3)2+, cis-Co(en)2(OSO2CF3)2+, and fac-Co(dien)(OSO2CF3)3, are reported. The use of these complexes as synthetic precursors for a range of complexes involving direct solvolysis or reactions in poorly coordinating solvents such as sulfolane or acetone is described. For example, in the pentaamminecobalt(III) system, syntheses of Co(NH3)5Ln+ (L = OH2, NH3, OHCH3, OHCH2CH3, OHCH(CH3)2, NCCH3, OP(OCH3)3, OCH·N(CH3)2, OS(CH3)2, OC(NH2)2, NCNH2, -OOCCH3, -OOCCHCl2) in high yield are reported. The kinetics and the stereochemical course of aquation of the labile trifluoromethanesulfonato complexes and derivatives are reported.
Zhejiang Chemline International Co., Ltd.
Contact:+86-571-88062298
Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
JinTan Pingsheng Chemical Co.,Ltd
Contact:+86-519-82828200
Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Doi:10.1021/ja01265a046
()Doi:10.1016/j.ejmech.2018.07.005
(2018)Doi:10.1016/S0022-328X(96)06752-6
(1997)Doi:10.1016/0040-4039(91)80659-T
(1991)Doi:10.1016/S0022-328X(00)00662-8
(2001)Doi:10.1016/S0040-4039(02)02602-3
(2003)
