Phosphonate ester hydrolysis catalyzed by two lanthanum ions. Intramolecular nucleophilic attack of coordinated hydroxide and Lewis acid activation

DOI: 10.1021/ja00133a013

Source and publish data:

Journal of the American Chemical Society p. 7399 - 7411 (1995)

Update date:2022-08-03

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Authors:

Tsubouchi, Akira

Bruice, Thomas C.

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Article abstract of DOI:10.1021/ja00133a013

(8-Hydroxy-2-quinolyl)methyl (8-hydroxy-2-quinolyl)methyl phosphonate (I) has been synthesized as a model compound and investigated in terms of catalysis of hydrolysis by two metal ions in concert. The divalent metal ions, Zn²⁺, Ni²⁺

Full text of DOI:10.1021/ja00133a013

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