Enantioselective Allylic Substitution Catalyzed by Chiral palladium Complexes: Catalyst Structure and Possible Mechanism of Enantioselection

DOI: 10.1002/hlca.19950780202

Source and publish data:

Helvetica Chimica Acta p. 265 - 284 (1995)

Update date:2022-08-03

Topics:

Authors:

Matt, Peter von

Lloyd-Jones, Guy C.

Minidis, Alexander B. E.

Pfaltz, Andreas

Macko, Ludwig

et al. et al.

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Article abstract of DOI:10.1002/hlca.19950780202

Allylpalladium complexes with chiral bis(dihydrooxazole) ligands were studied as catalysts for the enantioselective allylic substitution reaction of rac-1,3-diphenylprop-2-enyl acetate (rac-5) with the anion of dimethyl malonate (Scheme 1).Using enantiome

Full text of DOI:10.1002/hlca.19950780202

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