Total synthesis of (+/-)-phosphonothrixin, a novel herbicidal antibiotic containing C-P bond.

DOI: 10.7164/antibiotics.48.1134

Source and publish data:

Journal of Antibiotics p. 1134 - 1137 (1995)

Update date:2022-08-03

Topics:

Authors:

Nakamura

Kimura Kimura

Kanno Kanno

Takahashi

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Article abstract of DOI:10.7164/antibiotics.48.1134

Phosphonothrixin (1) is a novel herbicidal agent produced by Saccharothrix sp. ST-888, with a unique structure possessing a C-P bond and an isoprene unit. The total synthesis of this antibiotic was accomplished from methyl (bromomethyl)acrylate in six steps.

Full text of DOI:10.7164/antibiotics.48.1134

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Product name:3-Dibenzyloxooxophosphorio-2-hydroxy-2-hydroxymethylpropionic acid methyl ester

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