Ni(II)-catalyzed regio- and diastereoselective allylation of Grignards reagents to chiral allylic cyclic carbonates

Article abstract of DOI:10.1080/00397919508015850

Reaction of chiral allylic cyclic carbonates with Grignards reagent in the presence of NiCl₂(dppe) as a catalyst afforded the alkylated (E)-allylic alcohols with high regio- and diastereoselectivity.

Full text of DOI:10.1080/00397919508015850

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Synthetic Communications: An
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Organic Chemistry
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Ni(II)-Catalyzed Regio- and
Diastereoselective Allylation
of Grignards Reagents to Chiral
Allylic Cyclic Carbonates
Suk Ku Kang a , Dong Gyu Cho a , Chan Hee Park a ,
Eun Young Namkoong a & Joon Seob Shin a
a Department of Chemistry , Sung Kyun Kwan
University , Natural Science Campus, Suwon,
440-746, Korea
Published online: 23 Sep 2006.
To cite this article: Suk Ku Kang , Dong Gyu Cho , Chan Hee Park , Eun Young
Namkoong & Joon Seob Shin (1995) Ni(II)-Catalyzed Regio- and Diastereoselective
Allylation of Grignards Reagents to Chiral Allylic Cyclic Carbonates, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 25:11, 1659-1667, DOI: 10.1080/00397919508015850
To link to this article: http://dx.doi.org/10.1080/00397919508015850
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