Novel Intramolecular Michael-type Reactions between Vinyldiphenylphosphine and Pentamethylcyclopentadienyl Coordinated to Rhodium(III): Formation and X-Ray Structures of Heptadentate 10-Electron Donor Ligands

DOI: 10.1039/c39950001629

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1629 - 1630 (1995)

Update date:2022-08-02

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Authors:

Barthel-Rosa, Luis P.

Catalano, Vincent J.

Nelson, John H.

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Article abstract of DOI:10.1039/c39950001629

The reaction between vinyldiphenylphosphine and <<(η⁵-C5Me5)RhCl2>2> proceeds via an intramolecular hydroalkyl addition to yield the two isomeric products 1a and 2a.

Full text of DOI:10.1039/c39950001629

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Product name:[(η(5)-C5Me3-1,2-[CH2CH2CH2P(C6H5)2]2)RhCl]Cl

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