Journal of the Chemical Society. Perkin transactions I p. 1913 - 1934 (1995)
Update date:2022-07-29
Topics:
Clayden, Jonathan
McElroy, Andrew B.
Warren, Stuart
Regioselective ring-openings of epoxy alcohols bearing a diphenylphosphinoyl (Ph2PO) group give diols which can undergo stereospecific Horner-Wittig elimination.This method was used to make allylic alcohols, unsaturated β-hydroxy sulfides, homoallylic alcohols and unsaturated amino acids, with control over their absolute (R,S), relative (syn,anti) and geometrical (E,Z) stereochemistry.
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