Convenient Synthesis of (+)-Decarestrictine L

DOI: 10.1246/cl.1995.43

Source and publish data:

Chemistry Letters p. 43 - 44 (1995)

Update date:2022-08-16

Topics: Asymmetric synthesis Column chromatography NMR spectroscopy Catalyst Enantioselective Organic chemistry Stereoselective Chemical Synthesis Chirality HPLC (High Performance Liquid Chromatography) convenient synthesis

Authors:

Nokami, Junzo

Taniguchi, Takuya

Ogawa, Yozo

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Article abstract of DOI:10.1246/cl.1995.43

(+)-Decarestrictine L was prepared via intramolecular 1,4-addition of the oxy-anion derived from trialkylsilyl ether with Bu4NF, to the internal γ-hydroxy enone functionality, formed by the reaction of p-chlorobenzenesulfinylpropan-2-one with R-5-t-butyld

Full text of DOI:10.1246/cl.1995.43

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