Journal of Molecular Catalysis A: Chemical p. 117 - 126 (2016)
Update date:2022-08-05
Topics:
Wang, Weili
Daran, Jean-Claude
Poli, Rinaldo
Agustin, Dominique
Molybdenum complexes with ONO tridentate Schiff base ligands based on salicylideneaminophenolato (SAP) backbone with OH substitution on the salicyl arene ring have been synthesized and characterized. The molecular structures of the full series of OH substituted molybdenum complexes were determined by X-ray crystallography as monomers stabilized by one solvent molecule, [MoO2L(D)]. All dimeric complexes [MoO2L]2 were tested for the epoxidation of cyclooctene and cyclohexene under organic solvent-free conditions using aqueous TBHP as oxidant. The position of the OH on the SAP-modified ligand influenced the catalytic activity of the respective complexes. DFT calculations for the catalytic cycle yield energy spans in agreement with the experimentally observed activity trend.
View MoreVanderArk International Limited
Contact:86-10-82437576
Address:Qing He
Shandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Contact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Hangzhou Zhenghan Biological Technology Co., Ltd.
Contact:86-571-88781753
Address:liangzhu yuhang hangzhou city
Jiangxi Hito Chemical Co., Ltd.
Contact:+86-792-3170318
Address:No. 6, Tianhong Ave., Xinghuo Industry Park, Yongxiu, Jiujiang, Jiangxi, China
Doi:10.1016/0223-5234(96)80371-0
(1996)Doi:10.1002/anie.200701455
(2007)Doi:10.1016/0040-4020(96)00245-1
(1996)Doi:10.1002/cber.19961290412
(1996)Doi:10.1002/hlca.19960790214
(1996)Doi:10.1016/0040-4039(96)00352-8
(1996)