Enantioselective synthesis of 2-substituted 4-aminobutanoic acid (GABA) analogues via cyanomethylation of chiral enolates

DOI: 10.1039/p19960000621

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 621 - 627 (1996)

Update date:2022-08-05

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Authors:

Azam, Shamim

D'Souza, Alice A.

Wyatt, Peter B.

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Article abstract of DOI:10.1039/p19960000621

Cyanomethylation by bromoacetonitrile of sodium or lithium enolates derived from (4S,5R)-3-acyl-4-methyl-5-phenyl-1,3-oxazolidin-2-ones usually shows good stereoselecrivity; although the reaction of 3-(3-carboxypropanoyl)oxazolidinone 5d is exceptionally

Full text of DOI:10.1039/p19960000621

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