Alkenylvinylidene and allenylidene complexes: Evidence for the formation of a metal-trienylidene intermediate

DOI: 10.1039/CC9960001009

Source and publish data:

Chemical Communications p. 1009 - 1010 (1996)

Update date:2022-07-29

Topics:

Authors:

Bruce, Michael I.

Hinterding, Peter

Low, Paul J.

Skelton, Brian W.

White, Allan H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/CC9960001009

Reactions of [Ru(thf)(PPh₃)₂(η-C₅H₅)][PF ₆] with buta-1,4-diyne in the presence of nucleophiles give alkenylvinylidene or allenylidene complexes; the results are rationalised in terms of the formation of the intermediate trienylidene cation [Ru(C=C=C=CH₂)-(PPh₃)₂(η-C ₅H₅)]⁺ which undergoes nucleophilic addition at Cγ; the X-ray structure of the heteroallenylidene [Ru{C=C=CMe(NPh₂)}(PPh₃)₂(η-C ₅H₅)][PF₆] 2 is determined.

Full text of DOI:10.1039/CC9960001009

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:RuCCC(CH₂)P(C₆H₅)3(C₅H₅)(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-) = [RuCCC(CH₂)P(C₆H₅)3(C₅H₅)(P(C₆H₅)3)2]PF₆

Cas No:177985-83-0

R&D Labs maybe for 177985-83-0

Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Shanghai Goyic Pharmaceutical&Chemical Co,. Ltd

Contact:+86-021-60275964

Address:No. 528 ruiqing road
Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China

Relevant to this article

Complexes of unsymmetric bis-hydrazide ligands: Crystal structures and properties

Doi:10.1080/00958972.2012.708411
(2012)
General Approach for the Liquid-Phase Fragment Synthesis of Orthogonally Protected Naturally Occurring Polyamines and Applications Thereof

Doi:10.1021/acs.joc.9b02066
(2019)
Synthesis of racemic chiral-at-metal complexes of the Group 4 metals

Doi:10.1016/S0022-328X(00)00253-9
(2000)
Stereoselective Michael addition of thiophenols, amino acids and hydrazoic acid to (2S)-hydroxymethyl-dihydropyridone as a convenient route to novel azasugar derivatives

Doi:10.1016/S0040-4020(00)00563-9
(2000)
Doi:10.1021/jm00273a021
(1972)
Third-order nonlinear optical properties and crystal structures of N-(2-nitrobenzalidene)-2,4-dimethylaniline and N-(3-nitrobenzalidene)-2,4- dimethylaniline

Doi:10.1515/znb-2007-1113
(2007)

Article Doi