Stereoselective conjugate addition of carbon nucleophiles to chiral (E)-nitroalkenes bearing a γ-stereocenter. Origins of the observed anti selectivity

DOI: 10.1016/0040-4039(96)00468-6

Source and publish data:

Tetrahedron Letters p. 3055 - 3058 (1996)

Update date:2022-08-04

Topics:

Authors:

Ayerbe, Mirari

Morao, Inaki

Arrieta, Ana

Linden, Anthony

Cossio, Fernando P.

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Article abstract of DOI:10.1016/0040-4039(96)00468-6

The reaction between different organometallic carbon nucleophiles and chiral (E)-nitroalkenes has been studied. Anti selectivities have been observed in all cases. SCF-MO calculations suggest that the observed stereocontrol relies on the anti disposition of a donor group (methyl or hydrogen) with respect to the C-C bond in formation.

Full text of DOI:10.1016/0040-4039(96)00468-6

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