Journal of the Chemical Society. Perkin transactions I p. 383 - 388 (1996)
Update date:2022-07-29
Topics:
Naemura, Koichiro
Ueno, Koji
Takeuchi, Sachiko
Hirose, Keiji
Tobe, Yoshito
Kaneda, Takahiro
Sakata, Yoshiteru
Optically active azophenolic crown ethers 1 and 2 incorporating two cis-1-phenylcyclohexane-1,2-diol chiral subunits and a p-(2,4-dinitrophenylazo)phenol moiety as a chromophore have been prepared and the enantiomer recognitive coloration in complexation with chiral ethylamine and 2-aminoethanol derivatives has been examined. The observed enantiomer selectivities of crown ethers 1 and 2 have been interpreted on the basis of CPK molecular model examination of the diastereoisomeric complexes.
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