Russian Journal of General Chemistry p. 1493 - 1495 (2011)
Update date:2022-08-02
Topics: Silylation
Kirilin
Belova
Pletneva
Panfilova
Storozhenko
Sheludyakov
The N-siloxycarbonylation and transamination reactions were studied by an example of diazoles. We found that because of insufficient nucleophilicity of the nitrogen atoms in the first case only the sililylation process occurs, in the second case the low-boiling amine is replaced by the higher boiling one and the process is completed by the formation of O-silyluretans. Pleiades Publishing, Ltd., 2011.
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