Stereoselective synthesis of petrosterol and a formal synthesis of aragusterols

DOI: 10.1039/p19960002291

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2291 - 2296 (1996)

Update date:2022-08-05

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Authors:

Honda, Toshio

Katoh, Miho

Yamane, Shin-Ichi

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Article abstract of DOI:10.1039/p19960002291

Stereoselective construction of a steroidal side chain containing a 26-27 cyclopropane ring, compound 22, has been achieved by an intramolecular cyclisation of the corresponding β-methylsulfonyloxy cyanide 16, derived from a chiral cyclopentane derivative. Compound 22 has been further utilised in the synthesis of the naturally occurring steroid petrosterol 3.

Full text of DOI:10.1039/p19960002291

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