Structural requirements of an external, chiral amidophosphine ligand for asymmetric reaction of an organocopper reagent

DOI: 10.1016/0040-4039(96)01783-2

Source and publish data:

Tetrahedron Letters p. 7805 - 7808 (1996)

Update date:2022-08-05

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Authors:

Nakagawa, Yuichi

Kanai, Motomu

Nagaoka, Yasuo

Tomioka, Kiyoshi

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Article abstract of DOI:10.1016/0040-4039(96)01783-2

Three types of an external, chiral amide ligand, 2-6, were prepared and examination of their behavior in an asymmetric conjugate addition reaction of lithium dimethylcuprate with chalcone revealed to possibility for steric tuning to realize high selectivity.

Full text of DOI:10.1016/0040-4039(96)01783-2

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