Polyhedron p. 291 - 295 (1997)
Update date:2022-08-04
Topics:
Barloy, Laurent
Ku, Swee Y.
Osborn, John A.
De Cian, Andre
Fischer, Jean
The reaction of the tridentate rigid ligand PNP (2,6-bis(diphenylphosphinomethyl)pyridine) with RuCl2(PPh3)3 led to the formation of two new ruthenium(II) complexes, RuCl2(PNP)(PPh3) (1) and [RuCl(MeCN)(PNP)(PPh3)]Cl (2), which were analytically and spectroscopically characterized. The X-ray diffraction study of 1 shows that the PNP ligand coordinates Ru in a meridional mode, and reveals some steric congestion within the complex. Copyright
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