Insertions of allenes into palladium-carbon bonds of complexes containing bidentate nitrogen ligands. Structural and mechanistic studies

DOI: 10.1021/om960790e

Source and publish data:

Organometallics p. 551 - 562 (1997)

Update date:2022-08-03

Topics:

Authors:

Delis, Johannes G. P.

Groen, Johannes H.

Vrieze, Kees

Van Leeuwen, Piet W.N.M.

Veldman, Nora

Spek, Anthony L.

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Article abstract of DOI:10.1021/om960790e

The insertion reactions of the allenes propadiene and 1,2-heptadiene in the Pd-C bond of complexes (Ndown curve signN)Pd(R)X (Ndown curve signN = 8-PQ, p-An-BIAN, i-Pr-DAB, p-An-DAB, i-Pr-PyCa; R = Me, C(O)Me, C(O)Ph, C(O)i-Pr; X = Cl, Br) have been inves

Full text of DOI:10.1021/om960790e

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Product name:Pd(C₁₂H₆(NC₆H₄OCH₃)2)(CH₂C(C(O)CH₃)CH(CH₂CH₂CH₂CH₃))⁽¹⁺⁾*Cl^(1-)=(Pd(C₂₆H₂₀N₂O₂)(C₉H₁₅O))Cl

Cas No:186136-97-0

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