
Journal of Fluorine Chemistry p. 145 - 147 (1996)
Update date:2022-08-03
Topics:
Katritzky, Alan R.
Qi, Ming
Wells, Adam P.
The introduction of trifluoromethylacetylene units into organic compounds has been further studied and extended. The direct reaction of two equivalents of Lithium Diisopropylamide with 2-bromo-3,3,3-trifluoropropene gave lithium trifluoromethylacetylide, the anion of which was trapped in greater than 90% overall yield with a variety of electrophiles.
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(1952)