Synthesis of a stable sulfenic acid by oxidation of a thiol bearing a novel bowl-type substituent and its redox reactions

Article abstract of DOI:10.1080/10426509708545531

A stable sulfenic acid bearing a novel bowl-type substituent was synthesized by direct oxidation of a thiol, and its structure was determined by X-ray crystallographic analysis. The redox reactions of a sulfenic acid to a thiol and to a sulfinic acid, for which only those of transient species have been reported so far, were also demonstrated conclusively.

Full text of DOI:10.1080/10426509708545531

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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Synthesis of a Stable Sulfenic Acid
by Oxidation of a Thiol Bearing a
Novel Bowl-type Substituent and
Its Redox Reactions
Kei Goto , Michel Holler & Renji Okazaki
a Department of Chemistry, Graduate School of Science ,
The University of Tokyo 7-3-1 Hongo , Bunkyo-ku, Tokyo
113, Japan
b Department of Chemistry, Graduate School of Science ,
The University of Tokyo 7-3-1 Hongo , Bunkyo-ku, Tokyo
113, Japan
c Department of Chemistry, Graduate School of Science ,
The University of Tokyo 7-3-1 Hongo , Bunkyo-ku, Tokyo
113, Japan
Published online: 17 Mar 2008.
To cite this article: Kei Goto , Michel Holler & Renji Okazaki (1997) Synthesis of a Stable
Sulfenic Acid by Oxidation of a Thiol Bearing a Novel Bowl-type Substituent and Its Redox
Reactions, Phosphorus, Sulfur, and Silicon and the Related Elements, 120:1, 325-326, DOI:
10.1080/10426509708545531
To link to this article: http://dx.doi.org/10.1080/10426509708545531
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