
Tetrahedron Letters p. 2701 - 2704 (1997)
Update date:2022-08-03
Topics:
Nakagawa, Takayoshi
Hara, Noriyuki
Fujimoto, Yoshinori
Feeding of [13C2]acetate to hairy roots of Ajuga reptans var. atropurpurea followed by 13C-NMR analysis of the biosynthesized cholesterol and 20-hydroxyecdysone indicated that C-25 hydroxylation in 20-hydroxyecdysone biosynthesis mechanisms. Feeding studies of [26-13C]- and [27-13C]cholesterols established that the ratio of retention and inversion mechanisms is ca. 3:1.
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