A new series of organoboranes. IV. The participation of the 1,2-dicarbaclovododecaborane(12) nucleus in some novel heteratomic ring systems

Article abstract of DOI:10.1021/ic50010a005

Various chlorosilylcarborane derivatives were prepared. In subsequent reactions with amines or water a marked propensity for the formation of five-membered disilaazane and disilaoxane rings was exhibited. In reactions with dilithiocarborane, novel disilacyclohexane analogs were formed.