Tetrahedron Letters p. 3261 - 3264 (1997)
Update date:2022-08-04
Topics:
Abiko, Atsushi
Liu, Ji-Feng
Wang, Guo-Qiang
Masamune, Satoru
New chiral auxiliaries based on the bicyclic-isoxazolidine skeleton, 3-oxa-2,7-diazabicylo[3,3,0]octane derivatives, were synthesized in 60-80% overall yields from amino acids. Asymmetric alkylation and boron aldol reaction using the auxiliaries proceeded with high selectivities. 'Carboxylic amide' has been used for the asymmetric boron-mediated aldol reaction for the first time.
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(1997)Doi:10.1021/acs.jmedchem.0c01514
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(1996)
