Gas phase substituent effects. Stabilities of 1-aryl-2,2,2-trifluoroethyl cations

DOI: 10.1016/S0040-4039(00)94602-1

Source and publish data:

Tetrahedron Letters p. 685 - 688 (1990)

Update date:2022-08-03

Topics:

Authors:

Hishima, Masaaki

Inoue, Hiroki

Fujio, Mizue

Tsuno, Yuho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94602-1

Gas-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a ρ of -14.6.

Full text of DOI:10.1016/S0040-4039(00)94602-1

Products guided by the article

Product name:1-(1-Chloro-2,2,2-trifluoro-ethyl)-3-methyl-benzene

Cas No:191402-55-8

R&D Labs maybe for 191402-55-8

Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai

Relevant to this article

Effective construction of quaternary stereocenters by highly enantioselective α-amination of branched aldehydes

Doi:10.1039/c0ob00406e
(2010)
Reactions of 6-aminopyrimidines with biselectrophiles: Manipulation of product composition with solvent and pyrimidine substitution variation

Doi:10.1021/jo9713870
(1999)
C,H bond activation of imino substituted heterocycles: Synthesis and crystal structure of [μ₂-η³-( R) N-CH₂-C=C-C(H) =C(H)-X ]Fe₂( CO) ₆ and the isomeric clusters [μ₂-η³-(R)N-CH₂-C=C-X-C(R′)=C(R″)]Fe₂(CO)₆

Doi:10.1016/S0022-328X(96)06824-6
(1997)
Synthesis of 2-aryltryptamines with palladium catalyzed cross-coupling of 2-bromotryptamines and arylboronic acids

Doi:10.1016/S0040-4039(97)00797-1
(1997)
Variable-Valent Re≡NAr Species. A Family of Re^VINAr Amide Complexes and Their Re^vNAr Imine Precursors Related by Oxygen Atom Transfer

Doi:10.1021/ic9701322
(1997)
Reaction of 4-oxochromene-3-carboxaldehydes with primary amides and benzotriazole or 1H-1,2,4-triazole

Doi:10.1135/cccc19970781
(1997)

Article Doi