Tetrahedron Letters p. 685 - 688 (1990)
Update date:2022-08-03
Topics:
Hishima, Masaaki
Inoue, Hiroki
Fujio, Mizue
Tsuno, Yuho
Gas-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a ρ of -14.6.
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