Gas phase substituent effects. Stabilities of 1-aryl-2,2,2-trifluoroethyl cations

DOI: 10.1016/S0040-4039(00)94602-1

Source and publish data:

Tetrahedron Letters p. 685 - 688 (1990)

Update date:2022-08-03

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Authors:

Hishima, Masaaki

Inoue, Hiroki

Fujio, Mizue

Tsuno, Yuho

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Article abstract of DOI:10.1016/S0040-4039(00)94602-1

Gas-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a ρ of -14.6.

Full text of DOI:10.1016/S0040-4039(00)94602-1

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