Resolution of racemic carboxylic acid derivatives by Ti-TADDOLate mediated esterification reactions a general method for the preparation of enantiopure compounds

DOI: 10.1016/S0040-4020(97)00456-0

Source and publish data:

Tetrahedron p. 7539 - 7556 (1997)

Update date:2022-09-26

Topics:

Authors:

Seebach, Dieter

Jaeschke, Georg

Gottwald, Konstanze

Matsuda, Keiji

Formisano, Roberto

Chaplin, David A.

Breuning, Matthias

Bringmann, Gerbard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(97)00456-0

The Lewis-acid mediated transfer of an alkoxide ligand from the chiral ligand sphere of Ti-TADDOLates 1 to cyclic carboxylic acid derivatives is described. The kinetic resolution of dioxolanones, azlactones and biaryl lactones by the Ti-TADDOLates affords

Full text of DOI:10.1016/S0040-4020(97)00456-0

Products guided by the article

Product name:1,3-Dioxolan-4-one, 2,2-dimethyl-5-[4-(phenylmethoxy)phenyl]-

Cas No:192573-25-4

R&D Labs maybe for 192573-25-4

SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
Changsha Kamer Essence and Flavor Co.,Ltd

Contact:86-731-89832270

Address:No.327 Kangnin Road Changsha Bio Information Industry Park, Changsha city, Hunan province
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA

Relevant to this article

Chemistry of thioacylsilanes - Part 11. Cyclic and open chain α-silyl vinyl sulfides as precursors of thioannulated cyclopentenones and thiofunctionalized enones

Doi:10.1016/S0040-4020(97)00462-6
(1997)
Palladium-catalyzed one-pot approach to 3-(Diarylmethylene)oxindoles from propiolamidoaryl triflate

Doi:10.3390/molecules200814022
(2015)
Assessment of the activity of 8'diphenylphosphino-8'-methoxy-1,1'- binaphthyl as a ligand for palladium-catalyzed reactions

Doi:10.1248/cpb.45.1524
(1997)
Synthesis of 1-(4-isopropenylphenoxy)-bromo-C₂-C ₄-alkanes and application of their transformation products

Doi:10.1134/S1070427209100243
(2009)
Thermal stability or 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and related N-alkoxyamines

Doi:10.1021/ja9837102
(1999)
Structure and chemical properties of chlorohydrido(diarylsilyl)rhodium(III) complexes, mer-RhCl(H)(SiHAr₂)(PMe₃)₃. Thermally induced chloro transfer from rhodium to silicon in the complexes and silane exchange

Doi:10.1021/om970391z
(1997)

Article Doi