The β-heteroatom effect on carbenes

DOI: 10.1016/S0040-4020(97)00341-4

Source and publish data:

Tetrahedron p. 9989 - 9996 (1997)

Update date:2022-07-31

Topics:

Authors:

Lambert, Joseph B.

Liu, Xiaoyang

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Article abstract of DOI:10.1016/S0040-4020(97)00341-4

The β-thiophosphinoyl carbene PhCCH₂P(S)Ph₂ (5) has been prepared by irradiation of the corresponding diazo compound. The relative rates for insertion into the OH bond of methanol and for addition to the double bond of 2-methyl-2-but

Full text of DOI:10.1016/S0040-4020(97)00341-4

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